1FORTH

 

G. Zacharakis, H. Kambara, H. Shih, J. Ripoll, J. Grimm, Y. Saeki, R. Weissleder, and V. Ntziachristos, “Volumetric tomography of fluorescent proteinsthrough small animals in vivo”, PNAS 102, 18252 – 18257 (2005)

 

Abstract: Volumetric detection and accurate quantification of fluorescent proteins in entire animals would greatly enhance our ability to monitor biological processes in vivo. Here we present a quantitative tomographic technique for visualization of superficial and deep-seated (>2–3 mm) fluorescent protein activity in vivo. We demonstrate noninvasive imaging of lung tumor progression in a murine model, as well as imaging of gene delivery using a herpes virus vector. This technology can significantly improve imaging capacity over the current state of the art and should find wide in vivo imaging applications in drug discovery, immunology, and cancer research.

 

G. Zacharakis, J. Ripoll, R. Weissleder, and V. Ntziachristos, "Fluorescent protein tomography scanner for small animal imaging," IEEE Trans Med Imaging 24(7), 878-885 (2005).

 

Abstract: Microscopy of fluorescent proteins has enabled unprecedented insights into visualizing gene expression in living systems. Imaging deeper into animals, however, has been limited due to the lack of accurate imaging methods for the visible. We present a novel system designed to perform tomographic imaging of fluorescent proteins through whole animals. The tomographic method employed a multiangle, multiprojection illumination scheme, while detection was achieved using a highly sensitive charge-coupled device camera with appropriate filters. Light propagation was modeled using a modified solution to the diffusion equation to account for the high absorption and high scattering of tissue at the visible wavelengths. We show that the technique can quantitatively detect fluorescence with sub millimeter spatial resolution both in phantoms and in tissues. We conclude that the method could be applied in tomographic imaging of fluorescent proteins for in vivo targeting of different diseases and abnormalities.

 

K. Marias, J. Ripoll, H. Meyer, V. Ntziachristos, and S. Orphanoudakis, "Image analysis for assessing molecular activity changes in time-dependent geometries," IEEE Trans Med Imaging 24(7), 894-900 (2005).

 

Abstract: In vivo fluorescence molecular imaging and tomography has facilitated monitoring of genomics and proteomics over time and on the same animal. A highly important issue, however, has been the robust registration of animals imaged at different time points to obtain accurate description of activity and location. This paper presents a method for aligning temporal data of small animals based on surface anatomical features and improving the accuracy of monitoring fluorophore distribution. The method can account for differences in the positioning and compression of small animals and can be extended to three-dimensional as well as to other imaging modalities.

 

V. Ntziachristos, J. Ripoll, L. V. Wang, and R. Weissleder, "Looking and listening to light: the evolution of whole-body photonic imaging," Nat Biotechnol 23(3), 313-320 (2005).

 

Abstract: Optical imaging of live animals has grown into an important tool in biomedical research as advances in photonic technology and reporter strategies have led to widespread exploration of biological processes in vivo. Although much attention has been paid to microscopy, macroscopic imaging has allowed small-animal imaging with larger fields of view (from several millimeters to several centimeters depending on implementation). Photographic methods have been the mainstay for fluorescence and bioluminescence macroscopy in whole animals, but emphasis is shifting to photonic methods that use tomographic principles to noninvasively image optical contrast at depths of several millimeters to centimeters with high sensitivity and sub-millimeter to millimeter resolution. Recent theoretical and instrumentation advances allow the use of large data sets and multiple projections and offer practical systems for quantitative, three-dimensional whole-body images. For photonic imaging to fully realize its potential, however, further progress will be needed in refining optical inversion methods and data acquisition techniques.

 

A. Soubert, J. Ripoll, and V. Ntziachristos, "Accuracy of Fluorescent Tomography in the presence of heterogeneities: Study of the Normalized Born Ratio," IEEE Trans. Med. Imag. In press(2005).

 

Abstract: We study the performance of three-dimensional fluorescence tomography of diffuse media in presence of heterogeneities. Experimental measurements were acquired using an imaging system consisting of a parallel plate-imaging chamber and a lens coupled CCD camera, which enables conventional planar imaging as well as fluorescence tomography. To simulate varying degree of background heterogeneity we employed phantoms made of a fluorochrome tube surrounded by several absorbers in different combinations of absorption distribution. We show that the normalized Born approach accurately retrieves the position and shape of the fluorochrome even at high background heterogeneity. We also demonstrate that quantification is insensitive to a varying degree of heterogeneity and background optical properties. Findings are further contrasted to images obtained with the standard Born expansion and with a normalized approach that divides the fluorescent field with excitation measurements through a homogeneous medium.

 

G. M. Turner, G. Zacharakis, A. Soubret, J. Ripoll, and V. Ntziachristos, "Complete-angle projection diffuse optical tomography by use of early photons," Opt Lett 30(4), 409-411 (2005).

 

Abstract: We present the first, to our knowledge, experimental images of complex-shaped phantoms embedded in diffuse media by use of optical tomography. Imaging is based on a complete-angle projection tomographic technique that utilizes transmitted early photons. Results are contrasted with measurements obtained at later gates as well as pseudocontinuous-wave data. The scanning system developed employs noncontact illumination and detection technologies that allow for high spatial sampling of transmitted photons. Combining this system with complete-angle illumination is found to be an important strategy toward improved imaging performance, resulting in a better-posed inversion problem. The appropriateness of reconstruction algorithms similar to those employed in x-ray computed tomography are showcased, and suggestions for model improvements are provided.

 

H. Bahlouli, A. D. Alhaidari, and A. Al Zahrani, E. N. Economou, “Electromagnetic wave propagation in an active medium and the equivalent chrödinger equation with an energy-dependent complex potential” Phys. Rev. B 72, 094304 (2005)

 

ABSTRACT: We study the massless limit of the Klein-Gordon (K-G) equation in 1+1 dimensions with static complex potentials in order to provide an alternative, but equivalent, representation of plane electromagnetic (em) wave propagation in an active medium. In the case of a dispersionless em medium, the analogy dictates that the potential in the K-G equation is complex and energy dependent. We study also the nonrelativistic Schrödinger equation with a potential that has the same energy dependence as that of the K-G equation. The behavior of the solutions of this Schrödinger equation is compared with those found elsewhere in the literature for the propagation of electromagnetic plane waves in a uniform active medium with complex dielectric constant. In particular, both equations exhibit a discrepancy between the time-dependent and stationary results; our study attributes this discrepancy to the appearance of time-growing bound eigenstates corresponding to poles in the transmission and reflection amplitudes located in the upper half of the wave-number plane. The omission of these bound states in the expansion in stationary states leads to the observed discrepancy. Furthermore, it was demonstrated that there is a frequency- (energy) -and-size-dependent gain threshold above which this discrepancy appears. This threshold corresponds to the value of the gain at which the first pole crosses the real axis.

 

 

J. Zhou, Th. Koschny, M. Kafesaki, E. N. Economou, J. B. Pendry, and C. M. Soukoulis, “Saturation of the Magnetic Response of Split-Ring Resonators at Optical Frequencies”, Phys. Rev. Lett. 95, 223902 (2005)

 

ABSTRACT: We investigate numerically the limits of the resonant magnetic response with a negative effective permeability μeff for single-ring multicut split-ring resonator (SRR) designs up to optical frequencies. We find the breakdown of linear scaling due to the free electron kinetic energy for frequencies above_100 THz. Above the linear scaling regime, the resonance frequency saturates, while the amplitude of theresonant permeability decreases, ultimately ceasing to reach negative value. The highest resonancefrequency at which μeff < 0 increases with the number of cuts in the SRR. A LC circuit model providesexplanation of the numerical data.

 

 

G. Filippidis, C. Kouloumentas, G. Voglis, F. Zacharopoulou, T. G. Papazoglou, N. Tavernarakis “Imaging of Caenorhabditis elegans neurons by Second Harmonic Generation and Two-Photon Excitation Fluorescence.’’ Journal of Biomedical Optics 10, 024015 (2005)

 

ABSTRACT: Second-harmonic generation (SHG) and two-photon excitation fluorescence (TPEF) are relatively new and promising tools for the detailed imaging of biological samples and processes at the microscopic level. By exploiting these nonlinear phenomena phototoxicity and photobleaching effects on the specimens are reduced dramatically. The main target of this work was the development of a compact inexpensive and reliable experimental apparatus for nonlinear microscopy measurements. Femtosecond laser pulses were utilized for excitation. We achieved high-resolution imaging and mapping of Caenorhabditis elegans (C. elegans) neurons and muscular structures of the pharynx, at the microscopic level by performing SHG and TPEF measurements. By detecting nonlinear phenomena such as SHG and TPEF it is feasible to extract valuable information concerning the structure and the function of nematode neurons.

 

G. Filippidis, C. Kouloumentas, D. Kapsokalyvas, G. Voglis, N. Tavernarakis, T. G. Papazoglou “Imaging of Caenorhabditis elegans samples and sub-cellular localization of new generation photosensitizers for Photodynamic Therapy, using non-linear microscopy.’’ Journal of Physics D: Applied Physics 38, 2625-2632 (2005)

 

ABSTRACT: Two-photon excitation fluorescence (TPEF) and second-harmonic generation (SHG) are relatively new promising tools for the imaging and mapping of biological structures and processes at the microscopic level. The combination of the two image-contrast modes in a single instrument can provide unique and complementary information concerning the structure and the function of tissues and individual cells. The extended application of this novel, innovative technique by the biological community is limited due to the high price of commercial multiphoton microscopes. In this study, a compact, inexpensive and reliable setup utilizing femtosecond pulses for excitation was developed for the TPEF and SHG imaging of biological samples. Specific cell types of the nematode Caenorhabditis elegans were imaged. Detection of the endogenous structural proteins of the worm, which are responsible for observation of SHG signals, was achieved. Additionally, the binding of different photosensitizers in the HL-60 cell line was investigated, using non-linear microscopy. The sub-cellular localization of photosensitizers of a new generation, very promising for photodynamic therapy (PDT), (Hypericum perforatum L. extracts) was achieved. The sub-cellular localization of these novel photosensitizers was linked with their photodynamic action during PDT, and the possible mechanisms for cell killing have been elucidated.

 

D. Skalkos, E. Gioti, C.G. Stalikas, H. Meyer, T.G. Papazoglou, G. Filippidis Photophysical Properties of Hypericum Perforatum L. Extracts - Novel Photosensitizers for PDT ’’ Journal of Photochemistry and Photobiology B: Biology 82, 146-151 (2006)

 

ABSTRACT: We report the preparation of the methanolic extract (ME), and polar methanolic fraction (PMF) from the plant Hypericum perforatum L. The extracts contain various photosensitizing constituents such as naphthodianthrone derivatives (in 1.37% w/w), and chlorophylls (in 0.08% w/w). Upon light emission these constituents can be activated, providing photodynamic properties to the extracts, and making them a potent, new class, natural photosensitizers for use in photodynamic therapy (PDT), and photodynamic diagnosis (PDD). The absorbance spectra of the extracts are similar to the spectrum of hypericin, the main naphthodianthrone identified within, with two major bands at 548 and 590 nm. The fluorescence spectra in ethanol exhibit two main bands around 595 and 640 nm, in accordance with the spectrum of pure hypericin. The fluorescence intensity of PMF at 595 nm is only eight times less than the intensity of pure hypericin at the same wavelength, even though its hypericin concentration is only 0.57% w/w. The dependence of the PMF fluorescence signal on the pH of the medium, alone and in comparison with the signal of hypericin, has been investigated. PMF signal fades steadily, and smoothly both in acidic, and basic environment.

 

 

 

2ULUND

 

J. Swartling, J. Svensson, D. Bengtsson, K. Terike, and S. Andersson-Engels, 2005 Fluorescence spectra provide information on the depth of fluorescent lesions in tissue, Applied Optics  44(10), 1934-1941

 

Abstract: The fluorescence spectrum measured from a fluorophore in tissue is affected by the absorption and scattering properties of the tissue, as well as by the measurement geometry. We analyze this effect with Monte Carlo simulations and by measurements on phantoms. The spectral changes can be used to estimate the depth of a fluorescent lesion embedded in the tissue by measurement of the fluorescence signal in different wavelength bands. By taking the ratio between the signals at two wavelengths, we show that it is possible to determine the depth of the lesion. Simulations were performed and validated by measurements on a phantom in the wavelength range 815930 nm. The depth of a fluorescing layer could be determined with 0.6-mm accuracy down to at least a depth of 10 mm. Monte Carlo simulations were also performed for different tissue types of various composition. The results indicate that depth estimation of a lesion should be possible with 23-mm accuracy, with no assumptions made about the optical properties, for a wide range of tissues.

 

J. Svensson and S. Andersson-Engels, 2005, Modeling of spectral changes for depth localization of fluorescent inclusion, Optics Express 13(11), 4263-4274

 

Abstract: We have performed modeling of fluorescence signals from inclusions inside turbid media to investigate the influence of a limited fluorescence contrast and how accurately the depth can be determined by using the spectral information. The depth was determined by forming a ratio of simulated fluorescence intensities at two wavelengths. The results show that it is important to consider the background autofluorescence in determining the depth of a fluorescent inclusion. It is also necessary to know the optical properties of the tissue to obtain the depth. A 20% error in absorption or scattering coefficients yields an error in the determined depth of approximately 2-3 mm (relative error of 10-15%) in a 20 mm thick tissue slab.

 

J. Svensson, J. Axelsson, A. Garofalakis, H. Meyer, S. Andersson-Engels, 2005, Fluorescence spectroscopy in tissue phantoms for depth estimation in tissue imaging, Submitted to Journal of Biomedical Optics

 

Abstract: One way of determining the depth of a fluorescent inclusion is to detect fluorescent light that has propagated through the medium at two different wavelength bands, in which case a ratio can be calculated between the corresponding intensities. The wavelength regions should be chosen such that there is a difference in the attenuation in the medium. The method could be used to determine the depth of deep-lying tumors marked with a fluorescent compound. The depth information obtained by the ratio could be used as a complement to other methods, for example to tomography, due to its straightforward implementation. In this study we have performed phantom measurements to determine the depth of a fluorescent object inside a tissue phantom. Fluorescence at multiple wavelengths was measured and a ratio of yellow to red fluorescence was calculated for different depths of a fluorescent inclusion in a 2.5 cm thick liquid phantom. The ratio showed a clear dependence on the depth of the object. In order to verify the performance of the method in a realistic situation, measurements were also performed in tissue, where autofluorescence is superimposed on the fluorescence from the inclusion, yielding encouraging results.

 

3UCL

 

M. Schweiger,  S. Arridge, O.Dorn, A. Zacharopoulos, V. Kolehmainen,Reconstructing absorption and diffusion shape profiles in optical tomography using a level set technique, Optics Letters, (in press), 2005.

 

J. Sikora, A. Zacharopoulos, A. Douiri, M. Schweiger, L. Horesh, S.R. Arridge and J. Ripoll, Photon propagation in multilayered Geometries,   Physics in Medicine and Biology (in press), 2005.

 

4UKM

 

Paper published in Invest Radiolgy 40(6): 321-7 (2005), Optical imaging of spontaneous breast tumors using protease sensing smart optical contrast agents

 

Abstract: Objectives:To determine if spontaneous breast cancer lesions can be detected by fluorescence reflectance imaging (FRI) and fluorescence mediated tomography (FMT) using protease-sensing optical probes.

Materials and Methods: Transgenic (FVB/N-TgN (WapHRAS)69Lin YSJL)) mice that spontaneously develop carcinomas of the breast were i.v. injected with a cathepsin-sensing fluorescent probe. FRI and FMT were performed 24 hrs after contrast injection and region of interest (ROI) analysis was performed. MR images were acquired for anatomical co-registration with the FMT data. Moreover, correlative immunohistochemistry and fluorescence microscopy were performed. Results: All tumor nodules were clearly delineated by FRI showing an average signal intensity of 380 +- 106 AU. Fluorescence of the animal could be clearly localized to the tumor by FMT. In accordance with the imaging findings immunohistochemistry confirmed cathepsin-B expression of the tumors and fluorescence microscopy revealed a strong Cy 5.5. deposition in the tissue.

Conclusions: FRI and FMT using smart protease sensing probes allow to detect experimental spontaneous breast cancers. Since the expression levels of various proteases correlate with patient outcome this technique may not only help to detect but also to differentiate breast cancers non-invasively.

 

Paper submitted to Radiology: In vivo quantification of av&#946;3-expression using fluorescence mediated tomography

 

Abstract: Purpose: To non-invasively image and quanitfy the expression of the integrin av?3- as a molecular marker of tumor angiogensis using planar and tomographic optical methods.

Material and Methods: An av?3-targeted peptide was labeled with the cyanine dye Cy 5.5. Binding of the optical tracer was tested on human melanoma (M21), HT-1080 fibrosarcoma and MCF-7 adenocarcinoma cells. M21 tumor bearing mice were i.v. injected with either unmodified Cy 5.5 or RGD-Cy 5.5. For competition studies 250 nmol of the non-labeled RGD-peptide were administered prior to the injection of RGD-Cy 5.5. All optical imaging studies were performed using 2-d planar fluorescence reflectance imaging (FRI) technology and 3-d fluorescence mediated tomography (FMT).

Results: In vitro the peptide-dye conjugate showed clear binding affinity to av?3-positive cells (M21, HT-1080) while av?3-negative cells (MCF-7) and pre-dosing of M21 cells with the free RGD-peptide revealed little to no fluorescence. In vivo M21 xenografts were clearly visualized by FRI up to 24 h after i.v. injection of RGD-Cy 5.5 revealing an up to 40% higher target-to-background ratio as compared to the non-modified dye. FMT allowed to quantitatively analyze fluorochrome distribution in deeper tissue sections showing an average fluorochrome concentration of 102 nM in the target tissue. Competition with the free peptide resulted in a significant reduction of fluorochrome concentration in the tumor tissue (appr. 41 nM) suggesting binding specificity of the probe in vivo.

Conclusion: RGD-Cy 5.5 combined with novel tomographic optical imaging methods allows to non-invasively image and quantify av?3-expression in vivo and may thus be a promising strategy for sensitive tumor detection.

 

5CRSA

 

R. Pierrat, J.-J. Greffet, R. Carminati and R. Elaloufi, 2005, "Spatial coherence in strongly scattering media", J. Opt. Soc. Am. A vol. 22, 2329-2337.

 

Abstract : We study the spatial coherence of an optical beam in a strongly scattering medium confined in a slab geometry. Using the radiative transfer equation, we study numerically the behavior of the transverse spatial coherence length in the different transport regimes. Transitions from the ballistic to the diffusive regimes are clearly identified.

 

R. Pierrat, J.-J. Greffet, R. Carminati, 2005, "Photon diffusion coefficient in scattering and absorbing media", J. Opt. Soc. Am. A, accepted for publication.

 

Abstract : We present a unified derivation of the photon diffusion coefficient for both steady-state and time-dependent transport in disordered absorbing media. The derivation is based on a modal analysis of the time-dependent radiative transfer equation. This approach confirms that the dynamic diffusion coefficient  is given by the random-walk result D=1/3 c l*, where l* is the transport mean-free path and c is the energy velocity, independently on the level of absorption. It also shows that the diffusion coefficient for steady-state transport, often used in biomedical optics, depends on absorption, in agreement with recent theoretical and experimental works. These two results resolve a recurrent controversy in light propagation and imaging in scattering media.

 

R. Carminati, C. Henkel, J.-J. Greffet and J.M. Vigoureux, 2005, "Radiative and non-radiative decay of a single molecule close to a metallic nanoparticle", Opt. Commun., accepted for publication.

 

Abstract : We study the spontaneous emission of a single emitter close to a metallic nanoparticle, with the aim to clarify the distance dependence of the radiative and non-radiative decay rates. We derive analytical formulas based on a dipole-dipole model, and show that the non-radiative decay rate follows a R^-6 dependence at short distance, where R is the distance between the emitter and the center of the nanoparticle, as in F?rster's energy transfer. The distance dependence of the radiative decay rate is more subtle. It is chiefly dominated by a R^-3 dependence, a R^-6 dependence being visible at plasmon resonance. The latter is a consequence of radiative damping in the effective dipole polarisability of the nanoparticle.  The different distance behavior of the radiative and non-radiative decay rates implies that the apparent quantum yield always vanishes at short distance. Moreover, non-radiative decay is strongly enhanced when the emitter radiates at the plasmon-resonance frequency of the nanoparticle.

 

M. Laroche, R. Carminati and J.-J. Greffet, 2005, "Resonant optical transmission through a photonic crystal in the forbidden gap", Phys. Rev. B vol. 71, 155113.

 

Abstract : We show that a slab of a photonic crystal whose thickness is 3.5 ?m can transmit 100% of an incident beam whose frequency lies in the forbidden gap. This phenomenon is not linked to a volume defect but to the resonant coupling of leaky surface modes at both interfaces.

 

M. Laroche, C. Arnold, F. Marquier, R. Carminati, J.-J. Greffet, S. Collin, N. Bardou and J.-L. Pelouard, 2005, "Highly directional radiation generated by a tungsten thermal source", Opt. Lett. vol. 30, 2623-2625.

 

Abstract : We report the design of a tungsten thermal source with extraordinarily high directivity in the near infrared, comparable to the directivity of a CO2 laser. This high directivity is the signature of the long-range correlation of the electromagnetic field in the source plane. This phenomenon is due to the resonant thermal excitation of surface-plasmon polaritons.

 

M. Thomas, J.-J. Greffet and R. Carminati, 2005, "Single-molecule fluorescence enhancement using a metallic nanoantenna", manuscript in preparation.

 

Abstract : The spontaneous emission of a single molecule is substantially modified close to a nanostructure. We study numerically the spectral behavior of the radiative and non-radiative decay rates, of the local-field factor and the apparent quantum yield in the vicinity of a metallic nano-antenna. We study the competition between fluorescence enhancement and quenching versus the experimental parameters (transition dipole orientation, emission spectrum, distance to the nano-antenna, etc).

 

6UAM

 

G. Cwilich, L.S. Froufe-Perez and J.J. Saenz (2005), Spatial wave intensity correlations in quasi-one-dimensional wires, Physical Review Letters, Submitted)

 

Abstract : Spatial intensity correlations between waves transmitted through random media are analyzed within the framework of the random matrix theory of transport. Assuming that the statistical distribution of transfer matrices is isotropic, we found that the spatial correlation function can be expressed as the sum of three terms, with distinctive spatial dependences. This result coincides with the one obtained in the diffusive regime from perturbative calculations, but holds all the way from quasi-ballistic transport to localization. While correlations are positive in the diffusive regime, we predict a transition to negative correlations as the length of the system decreases.

 

G. M. Sacha, A. Verdaguer, J. Mart?nez, J. J. Saenz, D. F. Ogletree, and M. Salmeron (2005), Effective tip radius in electrostatic force microscopy, Applied Physics Letters 86, 123101

 

Abstract : A method to determine the effective electrostatic tip radius of arbitrarily shaped conducting tips in atomic force microscopy is presented. The method is based on the finding that for conductive samples, the electrostatic force can be separated into two contributions: one from a constant background that depends only on the macroscopic shape of the tips cone or pyramid and cantilever, and another that depends only on the radius of curvature of the tip apex. Based on a simple theoretical expression derived from the generalized image charge method, we show that the tip radius can be directly determined from experimental force-distance characteristics. For irregular tip shapes, we show that the measured tip radius is the average of two principal curvatures, in agreement with tip shape images obtained by scanning electron microscopy.

 

Jeong Young Park, G. M. Sacha, M. Enachescu, D. F. Ogletree, R. A. Ribeiro, P. C. Canfield, C. J. Jenks, P. A. Thiel, J. J. Saenz, and M. Salmeron., Sensing Dipole Fields at Atomic Steps with Combined Scanning Tunneling and Force Microscopy, Physical Review Letters 95, 136802 (2005)        

 

Abstract : The electric field of dipoles localized at the atomic steps of metal surfaces due to the Smoluchowski effect were measured from the electrostatic force exerted on the biased tip of a scanning tunnelling microscope. By varying the tip-sample bias the contribution of the step dipole was separated from changes in the force due to van der Waals and polarization forces. Combined with electrostatic calculations, the method was used to determine the local dipole moment in steps of different heights on Au(111) and on the twofold surface of an Al-Ni-Co decagonal quasicrystal.

 

F. J. Garcia de Abajo and J. J. Saenz, Electromagnetic Surface Modes in Structured Perfect-Conductor Surfaces, Physical Review Letters 95, 233901 (2005)

 

Abstract : Surface-bound modes in metamaterials forged by drilling periodic hole arrays in perfect-conductor surfaces are investigated by means of both analytical techniques and rigorous numerical solution of Maxwells equations. It is shown that these metamaterials cannot be described in general by local, frequency-dependent permittivities and permeabilities for small periods compared to the wavelength, except in certain limiting cases that are discussed in detail. New related metamaterials are shown to exhibit exciting optical properties that are elucidated in the light of our simple analytical approach.

 

8IC

 

“Multidimensional Fluorescence Imaging”, Paul French, Pietre de Beule, Jose Requejo-Isidro, Christopher Dunsby, Peter M. P. Lanigan, James McGinty, Clifford B. Talbot, Daniel S. Elson, Ian Munro, Neil Galletly and Mark Neil Imaging and Microscopy, 7 (August 2005) 20-22

 

“Multidimensional Fluorescence Imaging Applied to Biological Tissue” Daniel S. Elson, Neil Galletly, Clifford Talbot, Jose Requejo-Isidro, James McGinty, Christopher Dunsby, Peter M. P. Lanigan, Ian Munro, Richard K. P. Benninger, Mark A. A. Neil, John Lever, Gordon W. Stamp, and Paul M. W. French  / Accepted for publication as a chapter in Annual Reviews in Fluorescence 2006

 

“Wide-Field Optically-Sectioned Fluorescence Lifetime Imaging using a Nipkow Disk Microscope and a Tunable Ultrafast Continuum Excitation Source” D. M. Grant, D. S. Elson, D. Schimpf, C. Dunsby, J. Requejo-Isidro, I. Munro, M. A. A. Neil and P. M. W. French, E. Nye and G. Stamp, P. Courtney  Accepted for publication in Optics Letters

 

9UA

 

van Munster, E.B. and Gadella Jr., T.W.J. (2005) Fluorescence lifetime imaging microscopy (FLIM) in Microscopic techniques (ed. Rietdorf J.) of the series Advances in Biochemical engineering/biotechnology vol 95 (series ed. Scheper, T.), Springer Verlag, Heidelberg,  pp 143-175.

 

Abstract: Fluorescence lifetime imaging microscopy (FLIM) is a technique to map the spatial distribution of nanosecond excited state lifetimes within microscopic images. FLIM systems have been implemented both in the frequency domain, using sinusoidally intensity-modulated excitation light and modulated detectors, and in the time domain, using pulsed excitation sources and time-correlated or time-gated detection. In this review we describe the different modes in which both frequency-domain and time-domain FLIM instruments have been constructed in wide-field and in point-scanning (confocal) microscopes. Also novel additional strategies for constructing FLIM-instruments are discussed.  In addition to technical implementation this chapter gives an overview of the application of FLIM in cell biological en biomedical studies. Especially for in situ protein-protein interaction studies using fluorescence resonance energy transfer (FRET), FLIM has proven to be a robust and established technique in modern cell biology. Other application areas including usage of lifetime contrast for ion-imaging, quantitative imaging, tissue characterization and medical applications are discussed.

 

van Munster, E., Kremers, G.-J., Adjobo-Hermans, M., Gadella Jr., T.W.J.  (2005) Fluorescence resonance energy transfer (FRET) measurement by gradual acceptor photobleaching, J. Microsc. 218: 253-262.

 

Abstract: Fluorescence resonance energy transfer (FRET) is an extremely effective tool to detect molecular interaction at suboptical lresolutions. One of the techniques for measuring FRET is acceptor photobleaching: the increase in donor fluorescence after complete acceptor photobleaching is a measure of the FRET efficiency. However, in wide-field microscopy, complete acceptor photobleaching is difficult due to the low excitation intensities. In addition, the method is sensitive to inadvertent donor bleaching, autofluorescence and bleed-through of excitation light. In the method introduced in this paper, donor and acceptor intensities are monitored continuously during acceptor photobleaching. Subsequently, curve fitting is used to determine the FRET efficiency. The method was demonstrated on cameleon (YC2.1), a FRET-based Ca 2 + indicator, and on a CFP-YFP fusion protein expressed in HeLa cells. FRET efficiency of cameleon in the presence of 1 mM Ca2+ was 31 ± 3%. In the absence of Ca2+ a FRET efficiency of 15 ± 2% was found. A FRET efficiency of 28% was found for the CFP-YFP fusion protein in HeLa cells. Advantages of the method are that it does not require complete acceptor photobleaching, it includes correction for spectral cross-talk, donor photobleaching and autofluorescence, and is relatively simple to use on a normal wide-field microscope. 

 

Schultz, C., Schleifenbaum, A., Goedhart, J. and Gadella Jr., T.W.J. (2005) Multiparameter imaging for the analysis of intracellular signaling, Chem. Biochem. 6: 1323-1330. 

 

Abstract: In biological experimentation and especially in drug discovery there is a trend towards more complex test systems. Cell-based assays are replacing conventional binding or enzyme assays more and more. This development is strongly driven by novel fluorescent probes that give insight into cellular processes. Target proteins are studied in their natural environment; this gives much more realistic test results, especially with respect to enzyme location and kinetics. However, in the complex environment of cells, many parameters contribute to the performance of the protein of interest. Therefore, it would be desirable to monitor simultaneously as many of the relevant cellular processes as possible. Here, we discuss the possibilities and limitations provided by multiparameter monitoring of cellular events with fluorescent probes. Some novel examples of the use of fluorescent probes and multiparameter imaging are shown.

 

Cremazy, F, Manders, E.M.M., Bastiaens, P.I.H., Kramer, G., Hager, G.L., van Munster, E.B., Verschure, P.J., Gadella Jr., T.W.J., and van Driel, R. (2005) Imaging in situ protein-DNA interactions in the cell nucleus using FRET-FLIM, Exp. Cell Res. 309, 390-396.

 

Abstract: Although the distribution of DNA-binding proteins inside the cell nucleus can be analyzed by immunolabeling or by tagging proteins with GFP, we cannot establish whether the protein is bound to DNA or not. Here, we describe a novel approach that allows imaging of the in situ interaction between a GFP-fusion protein and DNA in the cell nucleus, using fluorescence resonance energy transfer (FRET). We used fluorescence lifetime imaging microscopy (FLIM) as a reliable tool to detect protein in contact with DNA. The method was successfully applied to the DNA-binding proteins histone H2B and the glucocorticoid receptor and to the heterochromatin-associated proteins HP1? and HP1?.

 

Dhonukshe, P., Mathur, J., H?lskamp, M. and Gadella Jr, T.W.J., (2005) Microtubule plus-ends reveal essential links between intracellular polarization and localized modulation of endocytosis during division-plane establishment in plant cells, BMC Biology 3, 11. Published on internet http://www.biomedcentral.com/1741-7007/3/11

 

Abstract: Background: A key event in plant morphogenesis is the establishment of a division plane. A plant-  specific microtubular preprophase band (PPB) accurately predicts the line of cell division, whereas  the phragmoplast, another plant-specific array, executes cell division by maintaining this predicted  line. Although establishment of these specific arrays apparently involves intracellular repolarization  events that focus cellular resources to a division site, it still remains unclear how microtubules  position the cell division planes. Here we study GFP-AtEB1 decorated microtubule plus-ends to  dissect events at the division plane. 

Results: Early mitotic events included guided growth of endoplasmic microtubules (EMTs)  towards the PPB site and their coincident localization with endocytic vesicles. Consequently, an  endosomal belt lay in close proximity to the microtubular PPB at its maturation and was maintained  during spindle formation. During cytokinesis, EMTs radiated from the former spindle poles in a  geometrical conformation correlating with cell-plate navigation and tilt-correction.  Naphthylphtalamic acid (NPA), an inhibitor of polar auxin efflux, caused abnormal PPBs and shifted  division planes. 

Conclusion: Our observations reveal a spatio-temporal link between microtubules and  intracellular polarization essential for localized endocytosis and precise establishment of the  division plane in plants. Additionally, they implicate the growth regulator, auxin, in this important  cellular event.  

 

Dhonukshe, P., Baluška, F., Schlicht, M., Hlavacka, A., Šamaj, J., Friml, J. and Gadella (2005) Endocytosis of cell surface material mediates cell plate formation during plant cytokinesis. Dev. Cell, accepted

 

Abstract: Dividing plant cells perform a remarkable task of building a new cell wall within the cytoplasm in a matter of minutes. A long standing paradigm claims that this primordial cell wall, known as the cell plate, is generated by delivery of  newly synthesised material from Golgi apparatus-originated secretory vesicles. Here we show that in diverse plant species cell surface material including  plasma membrane proteins, cell wall components and exogenously applied endocytic tracers, are rapidly delivered to the forming cell plate. Importantly, this occurs even when de novo protein synthesis is blocked. In addition, cytokinesis-specific syntaxin KNOLLE as well as PM-resident proteins localize to endosomes which aggregate to initiate the cell plate. Furthermore, the rate of endocytosis is strongly enhanced during cell plate formation and its genetic or pharmacological inhibition leads to cytokinesis defects. Our results reveal that endocytic delivery of cell surface material significantly contributes to cell plate formation during plant cytokinesis.

 

Goedhart, J. & Gadella Jr., T.W.J. (2005) Analysis of oligonucleotide annealing by electrophoresis in agarose gels using sodium borate conductive medium. Anal. Biochem. 343:186-187.  

 

Abstract: Annealed oligonucleotides are often used to insert short DNA sequences of 1060 base pairs into a plasmid. In this way, short tags such as FLAG tags and oligohistidine tags, as well as user-deWned multiple cloning sites, can be created. The insertion of oligonucleotides is also of interest for creating plasmids that encode short hairpin RNA (shRNA)1 to knock-down genes [1]. The successful insertion of oligonucleotides depends on proper annealing of the complementary strands. Short doublestranded DNA is usually analyzed on polyacrylamide gels, which is not as easily performed as regular agarose gel electrophoresis [2]. Here we report on the analysis of oligonucleotide annealing by ordinary agarose gel electrophoresis using a recently described [3] novel conductive medium based on sodium borate.

 

11EMBL

 

Schultz, C., Schleifenbaum, A., Goedhart, J., Gadella, T. W. J. (2005) Multiparameter imaging for the analysis of intracellular signaling. ChemBioChem 6, 1323-1330.

 

In biological experimentation and especially in drug discovery there is a trend towards more complex test systems. Cell-based assays are more and more replacing conventional binding or enzyme assays. This development is strongly driven by novel fluorescent probes that are giving insight into cellular processes. Target proteins are studied in their natural environment, which gives much more realistic test results, especially with respect to enzyme location and kinetics. However, in the complex environment of the cell, many parameters are contributing to the performance of the protein of interest. Therefore, it would be desirable to monitor as many of the relevant cellular processes as possible simultaneously. Here, we discuss the possibilities and limitations provided by multiparameter monitoring of cellular events with the help of fluorescent probes. Some novel examples using fluorescent probes and multiparameter imaging are shown.

 

Wichmann, O., Wittbrodt, J., Schultz, C. (2005) A small molecule FRET probe to monitor PLA2 activity in cells and organisms, Angew. Chem. Int. Ed. Engl., in press.

 

Watching live: The FRET reporter PENN/SATE (FRET=fluorescence resonance energy transfer) is membrane-permeant and enters cells and small organisms by using a prodrug approach. Once inside cells the reporter is cleaved by phospholipases, which results in a 30-fold change in the emission ratio.

 

Brumbaugh, J., Schleifenbaum, A., Gasch, A., Sattler, M., Schultz, C. (2005) A dual parameter FRET probe for measuring PKC and PKA activity in living cells. J. Am. Chem. Soc., accepted.

 

Cell function is regulated by complex and often interdependent networks of signaling molecules. To accurately describe these networks, it is important to monitor multiple signals in parallel. To this end we have developed a genetically encoded, FRET-based probe that independently monitors both protein kinase A (PKA) and protein kinase C (PKC) activity in vivo. Artificial, as well as physiological stimulants produced a negative or positive change in FRET efficiency following PKA or PKC activation respectively. Mutations of the phosphate accepting amino acids of the PKC substrate yielded a probe that was sensitive to PKA activation alone.

 

Black, S. L., Stanley, W. A., Filipp, F. V., Bhairo, M., Verma, A., Wichmann, O., Sattler, M., Wilmanns, M., Schultz, C. (2005) Probing lipid and drug binding domains with fluorescent dyes. J. Med. Chem., submitted.

 

Abstract: A series of 2- and 3-OH Nile red dyes was prepared in order to generate water-soluble probes that could be used to probe lipid binding to proteins. Various substitutions in positions 2-/3-, 6-, and 7-, shifted wavelengths while maintaining the environmental sensitivity of Nile red. In order to increase the solubility of the dyes in aqueous solutions, we attached butyric acid groups to the 2- or 3-OH position. In addition, phenothiazine dyes, which exhibited particularly long excitation properties, were synthesized and tested for the first time. All dyes showed Stokes shifts of 70-100 nm and changes in excitation and emission of over 100 nm, depending on the hydrophobicity of the environment. Binding studies with bovine serum albumin and the non-specific lipid transfer protein SCP2, revealed emission changes of more than 30 nm upon binding to the protein and a five-fold increase in emission intensity. Titration of the dye-loaded proteins with various lipids or drugs replaced the dye and thereby reversed the shift in wavelength intensity. This allowed us to estimate the lipid binding affinity of the investigated proteins. For SCP2, isothermal calorimetry (ITC) data verified the titration experiments. NMR titration experiments of SCP2 with 1a revealed that the dye is bound within the lipid binding pocket and competes with lipid ligands for this binding site. These results give valuable insight into lipid and drug transport by proteins outside and inside cells.

 

14IBCH

 

Shkrob M.A., Yanushevich Y.G., Chudakov D.M., Gurskaya N.G., Labas Y.A., Poponov S.Y., Mudrik N.N., Lukyanov S., Lukyanov K.A. Far-red fluorescent proteins evolved from a blue chromoprotein from Actinia equina. Biochem. J. 2005, 392, 649-654. Cover illustration.

 

Abstract: Proteins of Green Fluorescent Protein (GFP) family demonstrate a great spectral and phylogenetic diversity. However, red-shifted GFP-like proteins are still of intense demand for both basic and applied science. To obtain GFP-like chromoproteins with red-shifted absorption we performed a broad search in blue-coloured Anthozoa species. We revealed specimens of Beadlet Anemone Actinia equina exhibiting a bright blue circle band at the edge of its basal disc. A novel blue chromoprotein aeCP597 with absorption maximum at 597 nm determining the colouration of the anemone basal disk was cloned. AeCP597 carries a chromophore chemically identical to that of well-studied red fluorescent protein DsRed. Thus, a strong 42-nm bathochromic shift of aeCP597 absorption compared to DsRed is determined by peculiarities of chromophore environment. Site-directed and random mutagenesis of aeCP597 resulted in far-red fluorescent mutants with emission maxima at up to 663 nm. The most bright and stable mutant AQ143 possessed excitation-emission maxima at 595 and 655 nm, respectively. Thus, aeCP597 and its fluorescent mutants set a new record of red-shifted absorption and emission maxima among GFP-like proteins.

 

Lukyanov K.A., Chudakov D.M., Lukyanov S., Verkhusha V.V. Photoactivatable fluorescent proteins. Nature Review Mol. Cell Biol. 2005, 6, 885-891.

 

Abstract: The fluorescence characteristics of photoactivatable proteins can be controlled by irradiating them with light of a specific wavelength, intensity and duration. This provides unique possibilities for the optical labelling and tracking of living cells, organelles and intracellular molecules in a spatio-temporal manner. Here, we discuss the properties of the available photoactivatable fluorescent proteins and their potential applications.

 

Chudakov D.M., Lukyanov S., Lukyanov K.A. Fluorescent proteins as a toolkit for in vivo imaging. Trends Biotechnol. 2005, 23, 605-613.

 

Abstract: Green fluorescent protein (GFP) from the jellyfish Aequorea victoria, and its mutant variants, are the only fully genetically encoded fluorescent probes available and they have proved to be excellent tools for labeling living specimens. Since 1999, numerous GFP homologues have been discovered in Anthozoa, Hydrozoa and Copepoda species, demonstrating the broad evolutionary and spectral diversity of this protein family. Mutagenic studies gave rise to diversified and optimized variants of fluorescent proteins, which have never been encountered in nature. This article gives an overview of the GFP-like proteins developed to date and their most common applications to study living specimens using fluorescence microscopy.

 

Chudakov D.M., Lukyanov K.A. (2005) Using photoactivatable GFPs to study protein dynamics and function. In Jorde, L.B., Little, P.F.R., Dunn, M.J. and Subramaniam, S. (Eds), Encyclopedia of Genetics, Genomics, Proteomics and Bioinformatics.  John Wiley & Sons Ltd: Chichester, pp. 2129-2137.

 

Abstract: Green Fluorescent Protein (GFP) from jellyfish Aequorea victoria, its mutants and homologues from other organisms have become an integral part of modern methodology in cell and molecular biology. GFP-like proteins represent the only genetically encoded fluorescent tags that can be widely used to label organisms, cells, organelles, and proteins. This review is focused on photoactivatable GFP-like proteins, i.e. proteins capable of many-fold increase of fluorescence intensity at certain excitation-emission wavelengths in response to irradiation with specific light. Photoactivatable tags make it possible to "switch-on" fluorescent signal by a beam of light in precisely chosen part of organism or cell in order to track movement of the labeled objects. The spectral properties and mechanisms of the photoactivation for the most experimentally useful photoconvertible proteins are described in detail.  In particular, we discuss GFP and its mutant PA-GFP, green-to-red convertible protein Kaede from a stony coral Trachyphyllia geoffroyi, and Kindling Fluorescent Protein (KFP) from a sea anemone Anemonia sulcata. Considerable progress is still required to enrich the palette of monomeric photoactivatable GFP-like proteins, that would extend the field of possible applications.

 

Bulina M.E., Chudakov D.M., Britanova O.V., Yanushevich Y.G., Staroverov D.B., Chepurnykh T.V., Merzlyak E.M., Shkrob M.A., Lukyanov S., Lukyanov K.A. Genetically encoded photosensitizer. Nature Biotech. 2005, in press.

 

Abstract: Photosensitizers are chromophores that convert light energy into reactive oxygen species (ROS) production. Photosensitizers are used for the precise protein inactivation in chromophore-assisted light inactivation (CALI) technique and for the light-induced cell killing in photodynamic therapy. Here we report KillerRed - the first fully genetically encoded photosensitizer developed from the green fluorescent protein homologue, Hydrozoa jellyfish chromoprotein anm2CP. KillerRed is capable of ROS generation upon green light irradiation. While known photosensitizers are chemical compounds that must be added into living systems exogenously, KillerRed offers an upgrade, for the first time providing internal photosensitizer generation. KillerRed demonstrates dramatic cell killing effect when expressed in Escherichia coli and can be applied for the precise eukaryotic cell killing. We also show that KillerRed works successfully in CALI technique, efficiently inactivating fused;-galactosidase in vitro as well as phospholipase C1-delta pleckstrin homology domain in eukaryotic cells.

 

15UC3M

 

A. D. Kim and M. Moscoso (2005) Light transport in two-layered tissues, Journal of Biomedical Optics, 10, 034015.

 

Abstract: We study theoretically light backscattered by tissues using the radiative transport equation. In particular we consider a two-layered medium in which a finite slab is situated on top of a half space. We solve the one dimensional problem in which a plane wave is incident normally on the top layer and is the only source of light. The solution to this problem is obtained formally by imposing continuity between the solutions for the upper and lower layers. However, we are interested solely in probing the top layer. Assuming that the optical properties in the lower layer are known, we remove it from the problem yielding a finite slab problem by prescribing an alternate boundary condition. This boundary condition is derived using the theory of Greens functions and is exact. Hence, one needs only to solve the transport equation in a finite slab using this alternate boundary condition. We derive an asymptotic solution for the case when the slab is optically thin. We extend these results to the three dimensional problem using Fourier transforms. These results are validated by comparisons with numerical solutions for the entire two-layered problem.

 

A. D. Kim and M. Moscoso (2005), Radiative transport theory for optical molecular imaging, accepted for publication in “Inverse Problems”

 

Abstract: We study the inverse fluorescent source problem for optical molecular imaging. In particular, we recover key properties of a fluorescent source inside a halfspace composed of a uniform absorbing and scattering medium from angularly resolved measurements at the boundary plane. We use the radiative transport equation to model the multiple scattering of light in tissues.  Using Green's function, given as an analytical expansion in plane wave solutions, we subtract contributions from the measured angular data due to surface sources yielding a quantity that depends only on the interior fluorescent source. We analyse this reduced problem and obtain explicit solutions for a point source and a voxel source. Using the point source and voxel source solutions, we estimate the locations, size and total strength of a general source. We perform numerical studies to validate

this theory as well as investigate modelling errors due to incorrectly asumed optical properties of the medium.

 

M. Schweiger, S. R. Arridge, O. Dorn, A. Zacharopoulos, V. Kolehmainen (2005), Reconstructing absorption and diffusion shape profiles in optical tomography using a level set technique, accepted by 'Optics Letters'

 

Abstract: A novel shape reconstruction algorithm for optical tomography is introduced which uses a level-set formulation for the

shapes. Evolution laws based on gradient directions for a cost functional are derived for two different level-set functions, one

describing the absorption and one the diffusion parameter, as well as for the parameter values inside these shapes.  Numerical experiments are presented in 2-D which show that the new method is able to simultaneously recover shapes and contrast values of absorbing and scattering objects embedded in a moderately heterogeneous background medium from simulated noisy data.

 

16-2EMCR-II

 

Schlacher, K., K. Leslie, C. Wyman, R. Woodgate, M. Cox, and M.F. Goodman. (2005) DNA polymerase V and RecA protein, a minimal mutasome.  Molec. Cell, 17, p. 561-572. 

 

Abstract: A hallmark of the Escherichia coli SOS response is the large increase in mutations caused by translesion synthesis (TLS).  TLS requires DNA polymerase V (UmuD2C) and RecA.  Here we show that pol V and RecA interact by two distinct mechanisms.  First, pol V binds to RecA through its UmuC subunit in the absence of DNA and ATP, and second through its UmuD subunit in the presence of DNA and ATP, without ATP hydrolysis.  DNA synthesis using RecA mutants with increased affinity for single-stranded DNA reveals that any additional RecA bound to DNA inhibits TLS.  Therefore, a RecA nucleoprotein filament is unlikely to be required for SOS mutagenesis.  The activity of polV in vitro is greatly diminished in the absence of RecA or in the presence of RecA1730, a mutant defective for pol V mutagenesis in vivo, suggesting that RecA is an obligate accessory factor that activates pol V for SOS mutagenesis.     

 

17-1CNB

 

David de Juan, Mario Mellado, Jose Miguel Rodriguez-Frade, Patricia Hernanz-Falcon, Antonio Serrano, Antonio del Sol, Alfonso Valencia, Carlos Martinez-A. and Ana Maria Rojas. A framework for computational and experimental methods: identifying dimerization residues in CCR chemokine receptors. Bioinformatics 21:13-18 (2005)

 

Hernanz-Falcon, P., Rodriguez-Frade, JM., Serrano, A., Martinez-A., C. and Mellado, M.

On the dimerization of CCR5.  Nat. Immunol. 6:535-536 (2005)      .

 

17-2ICMM

 

Juan Luis Garcia-Pomar and Manuel Nieto-Vesperinas, "Imaging of extended objects by a negative refractive index slab ".  New Journal of Physics 7, 160 (2005).

 

Using a finite element method, we numerically study the imaging of an extended object by slabs of media with negative refractive index (within an effective medium theory). We analyse the consequences of possible deviations of the refractive index of the slab from the archetypal value of n = -1. These variations are obtained by introducing losses in the material and also by changing the real part of n. In this way, we show how slight changes in the refractive index from n = -1 affect the resolution of the image of the extended object.

 

J. L. Garcia-Pomar and M. Nieto-Vesperinas,  "Waveguiding, collimation and subwavelength concentration in photonic crystals".  Optics Express 13, 7998 (2005).

 

By means of both finite elements and FDTD calculations, we demonstrate that a structure of photonic crystal, constituted by two dimensional arrays of dielectric cylinders in air, or viceversa, previously proposed as capable of producing negative refraction with superlensing properties and subsequently proved to lack this characteristic, do possesses however the property of giving rise to effects of total internal reflection that allow both waveguiding, bending and collimation with high intensity subwavelength concentration of wavefronts. This is a consequence of both the dominant propagation along the &#915;M direction due to diffraction, and of intensity localization in the cylinder regions as a result of the operating frequency being in the lower part of the bandgap, namely, in the so-called dielectric band.

 

P.C. Chaumet, A. Rahmani and M. Nieto-Vesperinas, "Photonic force spectroscopy on metallic and absorbing nanoparticles"

PHYSICAL REVIEW B 71, 045425 (2005).

 

We present a detailed study of the optical trapping and manipulation of nanoparticles with complex permittivity using an apertureless near-field probe. We use a three-dimensional, self-consistent description of the electromagnetic scattering processes that accounts for retardation and the intricate many-body interaction between the substrate, the particle, and the probe. We analyze the influence of absorption on the optical force. For metals we describe how the optical force spectrum is influenced by the optical response of the metal, and in particular by plasmon resonances. We find that the optical force spectrum can provide an intrinsic signature of the particle composition which can be used to achieve a material-selective trapping and nanomanipulation.

 

S. E. Sburlan, L. A. Blanco, and M. Nieto-Vesperinas, "Plasmon excitation in sets of nanoscale cylinders and spheres", Physical Review B (in press).

 

By means of the boundary element method, we calculate and interpret the spectral lineshapes and near field spatial distributions of sets of a few nanospheres and nanocylinders on illumination close to the plasmon polariton excitation wavelength. This collective behavior is studied versus that of one isolated particle. Comparisons with results from previous experiments are done.  As far as cylinders are concerned, our procedure goes beyond former calculations based on the quasi-electrostatic approximation and, hence, it is exact. It allows to address mixtures of a few of these particles with different sizes providing the configuration possesses axial symmetry. In particular, configurations with nanoantenna behavior are discussed. Finally, we discuss in terms of the direction of propagation and polarization of the incident wave, both the spectral and spatial field distributions of a chain of three self-similar metallic nanospheres whose plasmon eigenmodes were previously analytically obtained and whose properties of

nanofocusing were predicted.

 

 

 

17-3LFSP

 

S. Ioanid, Ming Bai and N. Garcia, etc. Light Collimation and focusing by a thin flat metallic slab, Opt. Lett. 30, 2317 (2005)

 

18-1KIP

 

H. Mathee et. al. (2005), 'Nanostructure of specific chromatin regions and nuclear complexes', Histochem Cell Biol (online available)

 

C. Wagner et. al. (2005), 'Beyond nanosizing: an approach to shape analysis of fluorescent nanostructures by SMI-microscopy', Optik (in press)